粉体工学会誌
Online ISSN : 1883-7239
Print ISSN : 0386-6157
ISSN-L : 0386-6157
51 巻, 7 号
選択された号の論文の5件中1~5を表示しています
論文
  • 鈴岡 健司, 加藤 和彦, 田平 泰規, 八島 勇, 飯島 志行, 神谷 秀博
    2014 年 51 巻 7 号 p. 500-507
    発行日: 2014/07/10
    公開日: 2014/07/16
    ジャーナル フリー
    The effect of synthesis temperature, pH condition, poly (vinyl alcohol) (PVA) addition and post synthesis treatment by H2O2 on the crystal phase and their electrical resistivity of the powder prepared through the hydrolysis reaction of tin chloride was investigated. A powder that has strong X-ray diffraction (XRD) pattern which corresponds to periodic layered structure and weak Sn3O2(OH)2 signals were obtained when the synthesis condition was controlled to 90℃ and pH=2.4~4.2 with PVA addition. The XRD peak intensity of the layered structure drastically reduced when PVA was not added or the synthesis temperature was below 50℃. It was also found that the Sn3O2(OH)2 phase could be transferred to SnO2-x when the additive content of H2O2 was nearly equivalent to Sn content. Among samples prepared under various pH values and temperatures, it was confirmed that the composite samples with stronger XRD diffraction signals from periodic layered structure possesses lower resistivity.
  • 永島 大, 石藏 利文
    2014 年 51 巻 7 号 p. 508-518
    発行日: 2014/07/10
    公開日: 2014/07/16
    ジャーナル フリー
    The smooth transfer of solids from upper stage to lower stage through a downcomer is important for a stable operation of multi-stage spouted beds. Behavior of gas and solids in a moving bed downcomer, which is fitted with an orifice at the bottom, under negative pressure gradient has been investigated experimentally for a spouted bed operation, using Geldart D particles as bed materials. For this study, a downcomer has been installed in a one-stage spouted bed.
    As the results, the limits of operating conditions for a stable operation of a spouted bed with a downcomer were determined experimentally. The limits were influenced by the pressure drop across the spouted bed at the minimum spouting, length of the downcomer and the pressure gradient of the moving bed in the downcomer. Also, the range of the operating conditions for stable operation was extended with decreasing the bed depth of the spouted bed. In addition, based on experimental observation, the moving bed flow pattern changed from stable flow to intermittent flow as the gas pressure gradient in a moving bed downcomer increased and the fact could be explained by the solids discharge model which expresses the gas and the particles flow in the vicinity of the orifice.
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