Authors designed a new method in which non-saponifiable matter content is indirectly obtained by the determinating technique of saponfication and acid values.
If
A
1 is the weight of fatty acids that compose glycerides,
A
2 is the weight of fatty acids that compose esters,
A
3 is the weight of free fatty acids,
G is the weight of glycerol that composes glycerides,
A? is the weight of alcohols that compose esters,
W
1 is the weight of water produced in glycerides formation,
W
2 is the weight of water produced in esters formation, H
y is the weight of hydrocarbons,
then the non-saponifiable fraction, a% may be represented with a equation (1).
Also fatty acid content in tested oil, b% and that in the mixture of fatty acids and nonsaponifiable matter, c% may be represented with equations (2) and (3). From these, equation (7) is obtained.
When b and c are be calculated from data of titration, a is easily obtained.
Authors' results are shown in Table II compared with that by the usual method.
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