In their previous paper (This Journal 20,254-263 (1967)), the authors reported on the graphical calculations of isothermal evaporating process at 25°C of the two kinds of brines, which were supposed to be of the representative composition of ion-exchange membrane brines, by means of equilibrium diagrams of the five-components system.
In the present paper, the concentrating process of the brine belonging to Nacl-KCl-MgCl
2-CaCl
2-CaSO
4-H
2O type was studied at 25°C. Two kinds of synthetic brines containing no calcium sulfate were prepared to be evaporated to various concentrations. Samples in higher concentration region were prepared by dissolving a calculated amount of corresponding chemicals in water, instead of concentration by actual evaporation. The compositions of the solutions were analyzed chemically. and the crystals deposited were identified by means of X-ray diffraction.
Having tried to verify the validity of graphical calculation by experiment, the authors concluded as follows.
1) The compositions of solutions obtained by evaporation were found to fairly well coincide with the calculated values.
2) The process of concentration was studied by plotting the observed values on an equilibrium diagrams. As the results the kinds of crystals identified were found to completely coincide with that on the diagram. However, the composition changes of the solutions was found to coincide fairly well with the crystallization path at first, but not so well at the end of the evaporation.
3) The observed values for the equilibrium at I and J points on the equilibrium diagram were found to be not in good accord with the values given in the work of D'Ans.
4) As the solubility of CaSO
4 in the solutions decreased rapidly after the beginning of deposition of NaCl, there was scarcely any effect on the solubility of the coexisting ions.
5) It was found that the specific gravity of the solutions was found to increase linearly with the concentration of chloride ions, during the evaporation, up to the specific gravity of 1.351.
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