As a model for the caking of salt particles, bridge formation processes between NaCl single crystals were observed using optical microscopy. Starting with a liquid bridge of NaCl aq. connecting two crystal plates, NaCl crystal growth was observed during the evaporation of water at room temperature, both on the liquid surface and at three-phase boundaries on the substrates. In a rare case, under lower relative humidity (32%), small crystals formed on the liquid surface connected with one another, forming a tubular solid bridge. In most cases, however, the crystal growth occurred mainly at the three-phase boundaries on the substrates. The crystals grew along the liquid surface, finally forming a tubular solid bridge. The bridge contained a substantial amount of solution inside, which later caused efflorescence growth along the contact line of the tubes grown from both sides. In low temperature experiments at –10°C with the same experimental setup, growth of NaCl·2H
2O crystals were observed in the solution. A mechanism for low temperature caking due to the crystal formation. With the addition of K
4 [Fe(CN)
6], an anti-caking agent, at room temperature, lots of pores were formed on the tubular wall of the NaCl bridge. Due to stabilization of {120} faces, the growth front of the wall most probably took a rugged shape, resulting in the formation of a fragile bridge. The functions of other anti-caking agents, namely, the water-retaining effect of CaCl
2 and isolation effect of basic magnesium carbonate, were also studied.
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