Bulletin of the Society of Salt Science, Japan
Online ISSN : 2187-0322
Print ISSN : 0369-5646
ISSN-L : 0369-5646
Volume 15, Issue 2
Displaying 1-5 of 5 articles from this issue
  • Michio NAKAYAMA, Tetsuo MATSUO
    1961Volume 15Issue 2 Pages 78-81
    Published: 1961
    Released on J-STAGE: May 17, 2013
    JOURNAL FREE ACCESS
    In the course of our experiments to seek new salts by the addion of (NH4)2SO4in various quantities to bittern at boiling point, we found out that besides (K, NH4)2SO4·2MgSO4which had already been reported, a new basic salt closely resembling 8 MgSO4·Mg(OH)2·8H2O in shape was separated.
    Though the constituents of the new basic salt were Mg, NH4, SO4, OH and H2O as the result of chemical analysis, it was difficult to determine its chemical formula; because the contents of NH4and OH were very small in comparison with those of Mg and SO4.
    It is very interesting to note that in spite of the fact that no basic substance was added to bittern the separated salt was basic. The specific gravity, thermogravimetric analysis and the X-ray diffraction patterns of the new salt were studied.
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  • Kohei SAITO
    1961Volume 15Issue 2 Pages 81-85
    Published: 1961
    Released on J-STAGE: May 17, 2013
    JOURNAL FREE ACCESS
    In salt maaufacure brine coacentration in evaporators is usually measured by a Báume's hydrometer. A correction msut be made for density change due to variation in temperature drop of brine and a mount of the suspended calcium sulfate. A nomograph, based on our experimental results, is presented here.
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  • Kohei SAITO, Mitsuo WAKIMOTO, Hiroshi KUSUMI, Takeshi HIRAISHI
    1961Volume 15Issue 2 Pages 86-89
    Published: 1961
    Released on J-STAGE: May 17, 2013
    JOURNAL FREE ACCESS
    Colloidal calcium carbonate in a proportion of 0.1% of salt is being added to “Kitchen Salt” of 99% NaCl as an anti-caking agent. Table-feeder is used for the addition. Main problems of design and operation of the table-feeder have been solved after several experiments.
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  • Akira FUKASAWA
    1961Volume 15Issue 2 Pages 89-95
    Published: 1961
    Released on J-STAGE: May 17, 2013
    JOURNAL FREE ACCESS
    Electrolytic production of magnesium basic hypochlorite (magnesium bleaching powder) from bittern containing a relatively large amount of sodium chloride (about 7%), was studied as the first process of the electrolytic utilization of bittern ingredients. By this process magnesium bleaching powder may be gained without any addition of alkali, because of OH ions formed on cathode.
    The highest available chlorine content of magnesiun bleaching powder obtained was about 39%.
    The most suitable temperature for electrolysis was about 30-40°C. The PbO2electrode used consisted solely of PbO2without any metallic lead base. Up to anode current density of about 0.2A/cm2, PbO2anode was found to be a suitable electrode for magnesium bleaching powder production by bittern electrolysis.
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  • Akira FUKASAWA
    1961Volume 15Issue 2 Pages 96-102
    Published: 1961
    Released on J-STAGE: May 17, 2013
    JOURNAL FREE ACCESS
    In the electrolytic production of magnesium bleaching powder from bittern containing a small amount of sodium chloride, it was found that the yield decreased remarkably, because of the increased acidity.
    Therefore, by the addition of alkali to the bittern, a good effect was expected. Magnesium hydroxide precipitates produced by the addition of sodium hydoxide, contaminate the magnesium bleaching powder gained, and lessen the available chlorine.
    So, the relations between the amount of sodium hydroxide added and concentrations of ClO-and ClO-3in electrolyte, pH of this solution and available chlorine increase of magnesium bleaching powder during electrolysis, were studied.
    The optimum amount of sodium hydroxide to be added was found to be one equivalent to hydrogen chloride produced during electrolysis. This amount of sodium hydroxide gave the highest yield and the highest avilable chlorine. The optimum pH was 7-7.3, and PbO2electrode as an anode was found to be suitable, also, in the alkaline solution.
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