In the electrolytic production of magnesium bleaching powder from bittern containing a small amount of sodium chloride, it was found that the yield decreased remarkably, because of the increased acidity.
Therefore, by the addition of alkali to the bittern, a good effect was expected. Magnesium hydroxide precipitates produced by the addition of sodium hydoxide, contaminate the magnesium bleaching powder gained, and lessen the available chlorine.
So, the relations between the amount of sodium hydroxide added and concentrations of ClO
-and ClO
-3in electrolyte, pH of this solution and available chlorine increase of magnesium bleaching powder during electrolysis, were studied.
The optimum amount of sodium hydroxide to be added was found to be one equivalent to hydrogen chloride produced during electrolysis. This amount of sodium hydroxide gave the highest yield and the highest avilable chlorine. The optimum pH was 7-7.3, and PbO
2electrode as an anode was found to be suitable, also, in the alkaline solution.
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