Demand for highly volatile lower-cost coals, such as sub-bituminous coal, is increasing because of the skyrocketing costs of coal. However, highly volatile coal tends to combust spontaneously during storage.
Because spontaneous combustion results from low-temperature oxidization of coal, it can be evaluated through oxygen absorption measurements. Although the BOD OxiTop method is used to measure the oxygen consumption of microorganisms, the applicability of this method to evaluation of the oxygen absorption of coal has been proven.
Measurements of the oxygen absorption rate for coals of several common types with different ranks using the OxiTop method revealed that the respective oxygen absorption rates for bituminous coal and sub-bituminous coal are 1.0×10
-4–2.5×10
-4 and 4.0×10
-4–5.0×10
-4 [m・mol-O
2/g-coal/hr].
Furthermore, a positive correlation between the O
2 absorption rate and atmospheric O
2 contents was confirmed experimentally.
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