The effects of MgO powder addition into permeable Al2O3 refractory containing TiO2 and Al2O3 as matrixes were investigated to improve the corrosion,penetration and thermal shock resistance.Al2O3・TiO2 was detected in all specimens.By adding MgO,Na2O・4MgO・15Al2O3 and MgO・Al2O3 were produced.The amount of MgO・Al2O3 increased as MgO addition increased.The grain boudary cracks decreased as MgO additon increased.This phenomenon was considered that the producing Na2O・4MgO・15Al2O3 and MgO・Al2O3 which were malnly produced around the aggregate prevented TiO2 from penetrating into the grain boundary.Bulk density increased and apparent porosity decresed as MgO content increases and then showed the opposite tendency above MgO content 5~7wt%.Corrosion resistance increased as MgO addition increased and was superior by about two times compared with no MgO addition.
Penetration thickness also decreased by MgO addition and showed a half of thickness compared with no MgO addition.MgO addition made strength and fracture energy increase,and these facts resulted in the improving both thermal shock fracture and thermal shock damage resistance.Particulary,the fact that the penetration thickness decreased by MgO addition suggested that it would possible to operate the stable bubbling without O2 cleaning.