For slide gate plate with a carbon component,a reduction firing method is applied to achieve superior characteristics.However,a part of the carbon material added,or a part of the binder used,vaporizes,which results in a porous structure.Usually,plates are impregnated to reduce their porosity and to gain strength.
Another method is to examine and adjust the raw material composition.However,there are not many cases reported which examine the grain size.
The present study shows that the material adjustment base(l on the closed packing theory results in a dense plate even with reduction firing.This is proved by the actual performance of the plate produced by this method, was successfully compared with that of an impregnated plate.
Accurate value of weight loss of magnesia carbon brick in air was obtained continuously with a thermobalance at 1273,1473 and 1673K.The rate of oxidation was studied kinetically by application of topochemical reaction model to the oxidation process.It was concluded that the oxidation process of magnesia carbon brick in air was mainly controlled by the diffusion of O2through the porous decarburized layer. Furthermore,the effective diffusion coefficients through the pores in the decarburized layer were 0.25-0.56×10-4 m2・s-1 and the activation energy of effective diffusion coefficient of O2 was 36,9 kJ・mol-1.