In order to meet with the requirement of automotive mass saving, high-strengthened helical coil spring has been increasing, so the improvement on corrosive resistance of coating becomes more important.
Although one of the most popular coating methods of helical coil springs is the anionic electro-deposited coating, it would be effective to change to the cationic electro-deposited coating, to obtain higher corrosive resistance.
However, while the coated material is anode in the anionic electro-deposited process, it is cathode in the cationic electro-deposited process like in the electro-plating.
Accordingly, in the cationic electro-deposition process, hydrogen gas is generated by the electrolysis of water at the surface of the coated material, so it has been considered that the coated material might possibly cause the hydrogen embrittlement.
This paper shows some experimental results for the helical coil springs coated by the cationic electro-deposited process. It is realized that they does not occlude the hydrogen gas and does not show any hydrogen embrittlement, as results of measuring the hydrogen gas by the several methods, the slow bending fracture test, and the delayed fracture test by the helical coil springs.
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