巻号一覧
69 巻, 1 号
選択された号の論文の14件中1～14を表示しています
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落合 英二1949 年 69 巻 1 号 p. 1-8
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーPDF形式でダウンロード (1927K) -
菅澤 重彦1949 年 69 巻 1 号 p. 8-14
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーPDF形式でダウンロード (1567K) -
落合 英二, 津田 恭介1949 年 69 巻 1 号 p. 15-21
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーPDF形式でダウンロード (1197K) -
吸收スペクトルより見たるエピステフアニンの構造富田 眞雄, 上尾 庄次郎, 澤 貞樹, 土居 嘉壽雄, 三輪 敏子1949 年 69 巻 1 号 p. 22-25
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーAbsorption spectrum of epi-stephanine was compared with those of a large number. of compounds of dihydro isoquinoline series in order to discuss the structure of epi-stephanine.抄録全体を表示PDF形式でダウンロード (674K) -
ヂ及びトリエチレングリコールの硝化に就て石黒 武雄, 加藤 貞武, 柳生 正見1949 年 69 巻 1 号 p. 25-27
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーExaminations were made of the nitration of diethlene- and triethylene-glycol by the use of acid mixtures of various conditions in the ranges of dehydration values of 1.61 to 5.00. The melting and boiling points, and specific gravity of diethylene-glycol dinitrate were determined. At a low pressure following equation can be given: logt=0.096logp+2.0534 where t is the boiling point in °C and p, vapor pressure in mm. Properties, specific gravity and boiling point of triethylene-glycol dinitrate were determined.抄録全体を表示PDF形式でダウンロード (601K) -
Sulfamino-pyrimidin誘導體の合成に就て 其二松川 泰三, 吉田 誠1949 年 69 巻 1 号 p. 27-33
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーTwelve kinds of 2-p-aminobenzene-sulfaminopyrimidine compounds were synthesized by the reaction of p-acetaminobenzene-sulfonamide and various compounds of 2-methyl (or ethyl)-mercaptopyrimidine.抄録全体を表示PDF形式でダウンロード (1172K) -
5,6-Dimethoxy-8 (δ-diethylamino-α-methyl-n-butyl)-amino-quinolineの合成立岡 末雄, 上柳 次三郎, 樹下 友治1949 年 69 巻 1 号 p. 33-36
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリー5-Halogen compounds of 6-methoxy-8-nitroquinoline obtained by the direct chlorination or bromination of the latter were methoxylated and reduced, by which 5, 6-dimethoxy-8-aminoquinoline was obtained. Condensation of this with α-diethylamino-δ-pentanone-diethylacetal to Schiff's base and subsequent reduction gave the objected compound listed in the subtitle. This gives crystalline salt by condensation with 2-hydroxycinchonic acid.抄録全体を表示PDF形式でダウンロード (899K) -
4-Diäthylaminobenzyl-phenylalkylaminについて新延 信吉1949 年 69 巻 1 号 p. 37-39
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーFive kinds of 4-diethylamihobenzyl-phenylalkyl-amine were newly synthesized and their local anaesthetic actions were tested by rabbits' cornea test and their toxicity (LD 50) with guinea pigs.抄録全体を表示PDF形式でダウンロード (708K) -
塚本 赳夫, 富永 敏夫, 高橋 順治1949 年 69 巻 1 号 p. 40-41
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーQuercetin was isolated from the alcohlic extract of the leaves of Euphoria Longana Lam., and was proved by mixed fusion as pentacetyl-quercetin. A glucoside assumed to be quercitrin was isolated from crude tannin but values did not coincide with the published facts. This was thoroughly methylated by diazomethane, decomposed by dil. H2SO4, and pale-yellow, methylated aglycone, m.p. 191-2°, was obtained. This was proved by mixed fusion to be 3-hydroxy-5, 7, 3′, 4′-tetramethoxyflavone, m.p. 192°, which was prepared from rutin obtained from the flowers of Sophora japonica L. This proved that the bonding of sugar was at 3-position so that the glucoside must inevitably be quercetin-3-rhamnoside, i.e. quercitrin. Although there is a slight differences in the melting point from that found in literature it must be quercitrin as was earlier found by Mr Ohta (J. Pharm. Soc., Formosa. 53 (1942)).抄録全体を表示PDF形式でダウンロード (560K) -
富永 敏夫1949 年 69 巻 1 号 p. 41-43
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーA glucoside was isolated from the alcoholic extract of the leaves of Leucaena glauca Benth. The yield, about 0.0% of the leaves. The aglycone of this glucoside is quercetin and the sugar, rhamnose, and quantitative determination proved this to be quercetin-monorhamnoside. Thorough methylation of this glucoside with an excess of diazomethane and subsequent hydrolysis gave 3-hydroxy-5, 7, 3′, 4′-tetramethoxy-flavone Which proves that the original glucoside was quercetin-3-rhamnoside, i.e. quercitrin.抄録全体を表示PDF形式でダウンロード (695K) -
2-Amino-5p-chlorobenzenesulfone-thiazole誘導體の合成大田 正樹, 須藤 六郎1949 年 69 巻 1 号 p. 43-47
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーSyntheses of the derivatives of 2-amino-5-p-chlorobenzene-mercapto- or -sulfone-thiazole from p-chloropheny-mercapto-ketone, -sulfone-ketone or -mercapto-acetal are explained. The latter 3 compounds are obtained by the condensation of p-chlorothiophenol or p-chlorobenzenesulfinic acid and chloro-acetone, chloro-acetophenone or bromacetal, respectively.抄録全体を表示PDF形式でダウンロード (875K) -
Arylmercapto-, 及びArylsulfone-ketoneに就て大田 正樹, 須藤 六郎, 佐藤 菊正1949 年 69 巻 1 号 p. 47-50
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリー1) Mechanisms of alkaline decomposition were observed of arylmercapto- and arylsulfone-ketones.
2) Halogenation of arylmercapto-acetone results in the substitution of halogen atom in the methylene radical situated next to S-atom. In the case of arylsulfone-acetone, however, halogen goes in the methylene radical next to -SO2- group which, under the presence of hydrogen halides, transits in majority of cases to the methyl radical at the end.
3) Halogen compounds of arylmercapto-ketone are generally unstable and decomposes upon heating with alcohol.抄録全体を表示PDF形式でダウンロード (817K) -
2-Phenylamino-4-p-tolylsulfonemethyl-thiazoleに就て大田 正樹, 加藤 武明1949 年 69 巻 1 号 p. 50-51
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーCondensation of the Na-salt of p-thiocresol and 2-phenylamino-4-chloromethylthiazole, obtained from phenylthiourea and dichloro-acetone, results in 2-phenylamino-4-p-toylmercaptomethylthiazole. Oxidation of the latter gives 2-phenylamino-4-p-tolylsulfonemethyl-thiazole, m.p. 158-9°, which coincides with a compound obtained by the condensation of phenylthiourea and α-bromo-α′-p-tolyl-sulfone-acetone. From these facts, it is clear that the substance obtained generally by the condensation of α-bromo-α′-arylsulfone-acetone and thiourea is a compound of 4-arylsulfonemethylthiazole.抄録全体を表示PDF形式でダウンロード (364K) -
Pyridin-N-oxydに對するグリニヤ試藥の反應落合 英二, 有馬 洪1949 年 69 巻 1 号 p. 51-54
発行日: 1949/01/15
公開日: 2010/02/19
ジャーナル フリーIn order to observe the reaction of Grignard reagents on pyridine-N-oxide and its derivatives, the author re-examined the studies made by Colonna (C. A. 30, 3420) on pyridine-N-oxide. Ethereal solution of phenyl-MgBr was added to the anhydrous benzene solution of pyridine-N-oxide. Treatment of reaction products revealed formations of α-phenylpyridine and diphenyl-dipyridyl, the latter being assumed as γ, γ′-dipyridyl. These results show that the reaction of pyridine-N-oxide and phenyl-MgBr proceeds as in (A) (Cf. Figure in the original text) forming α-phenylpyridine. Polymerization from (II) is difficult to realize, for the formation of diphenyldipyridyl and it is assumed that the reaction proceeds as in (B) through (III). Yields of α-phenylpyridine and diphenyldipyridyl are comparatively low and the ratio of their formation is about 8:5.抄録全体を表示PDF形式でダウンロード (836K)
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