巻号一覧
69 巻, 11 号
選択された号の論文の16件中1～16を表示しています
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中原 和郎1949 年 69 巻 11 号 p. 481-485
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーPDF形式でダウンロード (1099K) -
津田 恭介1949 年 69 巻 11 号 p. 486-488
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーPDF形式でダウンロード (554K) -
Sulfamino-pyrimidine誘導體の合成に就て その3松川 泰三, 太田 武八郎1949 年 69 巻 11 号 p. 489-491
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリー1) 2-Methylmercapto-4-methylpyrimidine, 2-hydroxy-4-methyl-pyrimidine hydrochloride and 2-chloro-4-methylpyrimidine were synthesized.
2) 2-Sulfanilamido-4-methylpyrimidine (Sulfamerazine) was synthesized with a good yield by the condensation of N4-acetyl-sulfanilamide and 2-chloro-4-methylpyrimidine under the presence of alkali carbonate.抄録全体を表示PDF形式でダウンロード (470K) -
Sulfamino-pyrimidine誘導體の合成に就いて その4松川 泰三, 太田 武八郎1949 年 69 巻 11 号 p. 491-493
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリー1) 2-Chloropyrimidine was synthesized.
2) 2-Sulfanilamido-pyrimidine (sulfadiazine) and 2-sulfanilamido-4, 6-dimethylpyrimidine (sulfamethazine) were synthesized with good yields by the respective condensation of N4-acetylsulfanilamide and 2-chloropyrimidine or 2-chloro-4, 6-dimethylpyrimidine.抄録全体を表示PDF形式でダウンロード (527K) -
松川 泰三, 白川 研藏1949 年 69 巻 11 号 p. 493-496
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーNitration of 4, 5-dimethyl-carbethoxyaminobenzene with nitrosulfuric acid chiefly gives 2-nitro-4, 5-dimethyl-carbethoxy-aminobenzene with some 6-nitro and 2, 6-dinitro derivatives. Hydrolyses of these nitro compounds give 2-nitro-, 6-nitro- and 2, 6-dinitro-4, 5-dimethylaniline, respectively.
Acetylation of 6-nitro-4, 5-dimethylaniline with a mixture of acetic anhydride and glacial AcOH gives a mono-acetate of m.p. 106-7° and a diacetate of m.p. 114-5°.抄録全体を表示PDF形式でダウンロード (720K) -
高橋 酉藏, 柴崎 壽一郎1949 年 69 巻 11 号 p. 496-497
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリー5-Nitro (amino)-pyrimidazole, 2-methyl-5-iodo-pyrimidazole and ethyl 2-methyl-5-iodo-pyrimidazole-3-carboxylate were synthesized from 2-amino-5-nitro (iodo)-pyridine.抄録全体を表示PDF形式でダウンロード (325K) -
高橋 酉藏, 千田 重男1949 年 69 巻 11 号 p. 498-499
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーBasic phenol alkyl ethers were synthesized by the condensation of methyl 3-allyl-4-hydroxyphenyl ether and methyl 4-allyl-5-hydroxyphenyl ether with β-diethylamino-ethyl chloride. Application of magnesium-ethyl bromide on diethylamino-acetone gives 1-diethylamino-2-methylbutanol-(2) which was changed to 1-diethylamino-2-methyl-2-chlorobutane. Condensation of C-allylguaiacol to the latter gave (β-diethylamino-α-methyl-α-ethyl)-ethyl 2-methoxy-6-allylphenyl ether.抄録全体を表示PDF形式でダウンロード (318K) -
秋谷 七郎, 能本 乙彦, 奧井 誠一1949 年 69 巻 11 号 p. 500-502
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーDistilled water radiated with supersonic waves obstructs colloidal formation of sulfur formed from Na2S2O3 and HCl, and prolongs the time required for its formation. This is due to the formation of nitrous acid by supersonic wave radiation, the acid oxidizing hyposulfate to sulfurous acid which contributes to the equilibrium system of H2S2O3⇔H2SO3+S.抄録全体を表示PDF形式でダウンロード (501K) -
太田 達男1949 年 69 巻 11 号 p. 502-503
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーFrom the seeds of Nandina domestica Thunb., 0.68% non-phenolic and 0.04% phenolic bases were obtained. 0.02% Alkaloid was obtained from its pericarp.
Protopine, m. p. 206°, was obtained from the fraction of crude methyl ether of domesticine in 0.044% yield against the seeds.抄録全体を表示PDF形式でダウンロード (318K) -
Thiazolylsulfon類の合成 そのI菅野 三郎, 大野 昌子1949 年 69 巻 11 号 p. 503-507
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーMethyl-promizole and hydroxy-promizole were synthesized by the condensation of p-nitrophenylsulfenyl chloride with 2-hydroxy-4-methylthiazole. The yield was better than the original method by Bambas.抄録全体を表示PDF形式でダウンロード (623K) -
Thiazolium化合體の新合成法について その1松川 泰三, 万木 庄次郎1949 年 69 巻 11 号 p. 508-510
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーA synthetic procedure for vitamin B1 was formulated in which 2-methyl-4-amino-5-formaminomethyl-pyrimidine hydrochloride, γ-aceto-γ-chloropropyl acetate and H2S are used. Good results can be obtained by this reaction by the addition of ca. 15% active charcoal or active charcoal to which metals, such as ferric hydroxide or nickel hydroxide, have been adsorbed in 1% amount. It is assumed that in this reaction, the 3 component compounds undergo condensation in one stage and is peculiarly different from the methods heretofore used. It is necessary, in this reaction, that there be an amino radical at 4-position of pyrimidine nucleus.抄録全体を表示PDF形式でダウンロード (587K) -
Diphenylsulfide化合體の生成について その1松川 泰三, 太田 武八郎, 白川 研藏1949 年 69 巻 11 号 p. 510-513
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーAs a result of studies on the reaction mechanism involving the formation of p, p′-dinitro-diphenyl disulfide (II) and p, p′-dinitro-diphenyl sulfide (III) from the reaction of 2mol. p-nitro-chlorobenzene (I) and 1mol. Na2S2, it was found that the compound (II), formed from (I) and Na2S2, was reduced further by Na2S2 to Na-salt of p-nitrothiophenol (IV) to which (I) again reacted to form (III).
By the application of above theory, 2mol. (I) and 1mol. Na2S were reacted in the presence of a small amount of Na2S2 and (III) was obtained with a good yield. In this case, (II) is first formed from (I) and Na2S2, to which Na2S reacts to form (IV) and at the same time, Na2S2 is produced, this substance being repeatedly used in the first reaction. (IV) and (I) react to form (III).抄録全体を表示PDF形式でダウンロード (852K) -
スルフアニルアミド等配體の抗菌性石館 守三, 岡野 定輔1949 年 69 巻 11 号 p. 513-518
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーTen isosteric compounds of sulfanilamide were synthesized by replacing one or both of the two amino groups by CH3, OH or Cl (instead of F). Their comparative bacteriostatic activities were tested against E. coli und Staphylococcus aureus. The order of the precedence of the compounds are given in Table I. These facts indicate that sulfanilamide is most active among compounds tested but it is only a matter of comparison and compounds physically similar also possess considerable activities.抄録全体を表示PDF形式でダウンロード (923K) -
p-アミノ安息香酸等配體の抗菌性石館 守三, 岡野 定輔1949 年 69 巻 11 号 p. 518-521
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーTwelve isosteric compounds of p-aminobenzoic acid were prepared by replacing the NH2- and OH- groups with CH3, NHOH- or Cl- radicals and their respective bacteriostatic activities were tested against E. coli and Staph. aureus. The relative bacteriostatic efficacies of the groups in positions R4 and R1 of R4-C6H4-SO2-R1 and R4-C6H4-CO-R1 type compounds are discussed (Cf. Tables)抄録全体を表示PDF形式でダウンロード (457K) -
p-アミノ安息香酸とその等配體類との拮抗石館 守三, 岡野 定輔1949 年 69 巻 11 号 p. 521-524
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーAntagonistic effects of the isosteric compounds of p-aminobenzoic acid against p-aminobenzoic acid on the growth of E. coli were studied. It was found that, while the 4-amino compounds were remarkably antagonistic against p-aminobenzoic acid, 4-hydroxyl and 4-methyl compounds were less effective and no such effect was found in 4-chloro compounds. Antagonistic properties of 4-nitro compounds against p-aminobenzoic acid are also discussed.抄録全体を表示PDF形式でダウンロード (505K) -
スルフアニルアミド等配體とp-アミノ安息香酸との拮抗石館 守三, 岡野 定輔1949 年 69 巻 11 号 p. 525-528
発行日: 1949/11/25
公開日: 2010/02/19
ジャーナル フリーThe mechanism of the specific action of sulfanilmide type compounds characterized by competition with p-aminobenzoic acid are discussed. In order to antagonize p-aminobenzoic acid, it is necessary for the molecule to possess on the one end, a radical which forms a hydrogen bond, and on the other, an ionizable radical such as the sulfonyl, carbonyl or arsenyl, in the para position to the former one, as well as the size and the shape of the whole molecule.抄録全体を表示PDF形式でダウンロード (695K)
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