In a last decade, various important antibiotics containing higher-carbon carbohydrates, such as tunicamycin, anthelmycin (hikizimycin), mildiomycin, ezomycin, octosyl acid, apramycin, lincomycin etc., have been discovered in fermentation broths of
Streptomyces species. Synthetic studies on higher-carbon carbohydrates of these antibiotics are reviewed
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