FeS2-Catalyzed Hydrocracking of Diarylmethanes

Xian-yong WEI; Eisuke OGATA; Etsuo NIKI

doi:10.1627/jpi1958.35.358

Journal of The Japan Petroleum Institute

Print ISSN : 0582-4664

FeS₂-Catalyzed Hydrocracking of Diarylmethanes

Xian-yong WEI, Eisuke OGATA, Etsuo NIKI

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Keywords: Coal liquefaction, Hydrocracking, Hydrogen-accepting ability, Resonance stability, Adsorption, Selectivity

JOURNAL FREE ACCESS

1992 Volume 35 Issue 4 Pages 358-361

DOI https://doi.org/10.1627/jpi1958.35.358

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Abstract

Hydrocracking reactions of diarylmethanes (DAMs) were carried out with FeS₂ at 300°C to examine the structural effect of DAMs on their reactivities toward hydrocracking. The reactivities were dominated by the hydrogen-accepting abilities of the ipso-carbons in DAMs and the resonance stabilities of the resulting arylmethyl radicals.

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