ISIJ International
Online ISSN : 1347-5460
Print ISSN : 0915-1559
ISSN-L : 0915-1559
Regular Article
Liquid–Solid Interface Free Energies for Metals from Free-volume Method and Interface Structural Model
Keiji Nakajima
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2006 Volume 46 Issue 6 Pages 795-800

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Abstract

The thermodynamic approximate-expression for liquid–solid interface free energy which has its origin in the loss of configurational entropy due to the adjustment of the liquid to a boundary was derived. Triangular-square-pentagonal lattices were proposed for a structural model of the liquid–solid interface. Calculated values from the thermodynamic approximate-expression and the interface structural model showed a fair agreement with previous experimental data.

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© 2006 by The Iron and Steel Institute of Japan
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