Journal of The Adhesion Society of Japan
Online ISSN : 2187-4816
Print ISSN : 0916-4812
ISSN-L : 0916-4812
Original Paper
Investigation of the Relaxation Spectrum of a Multi-component System by the Pulse Method NMR Part 4 Investigation of Silicone PSAs’TackProperties by Using Pulsed NMR and DMA
Yoshiaki URAHAMAYuki HAMADAHajime KISHIKeiko ITOYoshinobu NAKAMURA
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2011 Volume 47 Issue 3 Pages 98-105

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Abstract
The probe tack,the dynamic mechanical analysis (DMA),and the pulsed NMR of a silicone PSAs were measured. The elucidation of the behavior of a tack was tried from the relaxation spectrum and the dynamic mechanical analysis. From the analysis of the relaxation spectrum,it becomes clear that the value of a probe tack depend in a large part on the quantity of MQ resin that exists in a hard segment. DMA was measured in order to divide the behavior of this MQ resin into a contact process and a debonding process. In the contact process,the temperature at which E' was 10⁵Pa was converted into the temperature of probe tack measurement by using the WLF equation.Moreover,in a debonding process,probe tack measurement temperature is equivalent to a temperature low 80℃ in DMA measurement. Therefore,E'  is decreasing monotonously with  a rise in temperature. Thatis,in a debondingprocess,the value of a tack becomes large at low temperature. From a contact process and a debonding process,a probe tack will indicate the maximum value with the reduced temperature at which E' is10⁵Pa. This result isconforming to the evaluated result of a probe tack.
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© 2011 The Adhesion Society of Japan
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