Analytical Sciences: X-ray Structure Analysis Online
Online ISSN : 1348-2238
Part 3
Crystal Structure of Bis(μ2-azido)-tetrakis(triphenylphosphine)-di-silver(I)
Aliakbar Dehno KHALAJIMehdi AMIRNASRLarry R. FALVELLOTatiana SOLER
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Volume 22 (2006) Pages x47-x48

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Abstract

The title complex, [(PPh3)2Ag(μ-N3)2Ag(PPh3)2], has been synthesized and structurally characterized by single-crystal X-ray diffraction. The silver atoms are joined through a double μ1,3-azido (N3) bridge. To each silver atom are also coordinated two P atoms from two triphenylphosphine molecules. The coordinated polyhedron around silver is a distorted tetrahedron.

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© 2006 by The Japan Society for Analytical Chemistry
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