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Analytical Sciences: X-ray Structure Analysis Online
Vol. 22 (2006) P x49-x50

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http://doi.org/10.2116/analscix.22.x49

Part 3

The title complex, [(ca2ph)Cu(μ-I)2Cu(ca2ph)] {ca2ph = N,N′-bis(trans-cinnamaldehyde)-phenylenediimine}, has been synthesized and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two copper(I) ions are doubly bridged by iodine substituents. The ca2ph acts as a bidentate ligand coordinating via two N atoms to the copper. The coordination geometry around the Cu atom is a distorted tetrahedron formed by two N atoms from ca2ph and two iodine substituents. The distance between the two copper atoms is 2.5992(15)Å.

Copyright © 2006 by The Japan Society for Analytical Chemistry

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