Analytical Sciences: X-ray Structure Analysis Online
Online ISSN : 1348-2238
ISSN-L : 1348-2238
Part 3
Crystal Structure of Di-μ-iodo-bis[N,N′-bis(trans-cinnamaldehyde)-phenylenediimine]copper(I)
Aliakbar Dehno KHALAJIMehdi AMIRNASRRichard WELTER
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JOURNALS FREE ACCESS

2006 Volume 22 Pages x49-x50

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Abstract

The title complex, [(ca2ph)Cu(μ-I)2Cu(ca2ph)] {ca2ph = N,N′-bis(trans-cinnamaldehyde)-phenylenediimine}, has been synthesized and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two copper(I) ions are doubly bridged by iodine substituents. The ca2ph acts as a bidentate ligand coordinating via two N atoms to the copper. The coordination geometry around the Cu atom is a distorted tetrahedron formed by two N atoms from ca2ph and two iodine substituents. The distance between the two copper atoms is 2.5992(15)Å.

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© 2006 by The Japan Society for Analytical Chemistry
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