The title complexes, [Ag(bpy)(PPh3)]X (1: X = PF6, 2: X = ClO4), contain a bidentate 2,2′-bipyridine (bpy) ligand and a monodentate triphenylphosphine (PPh3) ligand, which were determined by the X-ray diffraction method. The coordination geometry of the Ag atom is distorted trigonal with two N atoms from 2,2′-bipyridine and one P atom from triphenylphosphine (PPh3).
