Analytical Sciences: X-ray Structure Analysis Online
Online ISSN : 1348-2238
ISSN-L : 1348-2238
Part 7
Crystal Structure of [Fe(bpy)3][Fe(pydc)2]2(pydcH2)1/2·6.5H2O Complex (bpy = 2,2′-bipyridine, pydc = pyridine-2,6-dicarboxylate)
Hossein AGHABOZORGFahimeh MOHAMAD PANAHElahe SADR-KHANLOU
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2007 Volume 23 Pages x139-x140

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Abstract
The crystal structure of the title compound shows three complexes as anionic and cationic parts, where all of them are six coordinated. Crystallization was occurred in the triclinic system, space group P1 with a = 14.0445(9)Å, b = 14.8834(10)Å c = 17.4394(12)Å, α = 65.3880(10)°, β = 69.457(2)°, γ = 85.997(2)°, V = 3090.9(4)Å3, Z = 2. In the formation of this crystal, metal-ligand coordinations, hydrogen-bonding (O-H…O and C-H…O) and ion-pairing throughout the lattice play important roles in stabilizing the three-dimensional network.
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© 2007 by The Japan Society for Analytical Chemistry
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