The crystal structure of Ir(1-piq)2(pic-3-OH) (1-piq = 1-phenylisoquinoline, pic-3-OH = 3-hydroxypicolinate) was determined by X-ray crystallography. The complex crystallized in the triclinic system, space group P1, with a = 10.6477(7)Å, b = 11.9891(8)Å, c = 14.7693(9)Å, α = 94.758(1)°, β = 105.936(10)°, γ = 114.140(1)°, Z = 2, V = 1612.92(18)Å3, and R = 0.0305. The crystal structure consists of a distorted octahedral geometry around the iridium.
