Analytical Sciences: X-ray Structure Analysis Online
Online ISSN : 1348-2238
ISSN-L : 1348-2238
Part 4
Synthesis and Structural Characterization of Bis[2-dimethylamino-α-trimethylsilylbenzyl]Mn(II)
Hongbo TONGDiansheng LIU
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2008 Volume 24 Pages x67-x68

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Abstract

Mn[2-NMe2-α-SiMeC6H4]2 (I) is triclinic, P1. The unit-cell dimensions at 203 K are a=9.318(2)Å, b=10.781(3)Å, c=13.453(3)Å, α=88.87(3)°, β=88.34(3)°, γ=76.91(2)°, V=1315.8(6)Å3, Dx =1.181 g/cm3, and Z = 2. The final R value is 0.072 for 3442 measured reflections with I > 2σ(I). The structure is synthesized by the reaction of MnCl2 with 2-dimethylamino-R-trimethylsilylbenzyl-Li. The central Mn(II) metal has four coordination sites by forming a distorted tetrahedron.

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© 2008 by The Japan Society for Analytical Chemistry
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