Crystal Structure of Aqua[N,N′-bis(3-methoxysalicylidene)propane-1,2-diaminato]methanolmanganese(III) Perchlorate

Abstract

The title compound, a hydrogen-bonded pseudo-dimer, Mn(C₁₉H₁₈N₂O₄)(CH₄O)(H₂O)]ClO₄, (I), has been structurally characterized. Complex (I) affords an elongated octahedral coordination environment, with axial Mn-O(CH₃OH) = 2.296(5) and Mn-O(water) = 2.208(3)Å.