Abstract
Fixed-bed adsorption experiments of laboratory-scale were carried out to remove organic solvent vapors by Y-type zeolite adsorbent. Some of binary adsorption equilibria of azeotropic mixture-HSZ systems showed two azeotropic points. Breakthrough curve could be simulated using the Stop & Go method for these systems. Those experiment data were compared with molecular simulation by the Grand Canonical Monte Carlo (GCMC) method.