The Journal of Biochemistry
Online ISSN : 1756-2651
Print ISSN : 0021-924X
AUTOÖXIDATION OF L-ASCORBIC ACID AND IMIDAZOLE NUCLEUS
I. THE EFFECTS OF IMIDAZOLE DERIVATIVES ON THE AUTOÖXIDATION OF L-ASCORBIC ACID
YUJIRO IMANAGA
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1955 Volume 42 Issue 6 Pages 657-667

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Abstract
1. The effects of imidazole derivatives on the autoöxidation of L-ascorbic acid were studied.
At pH 7.1, imidazolecarboxylic acid was the most accelerative, while methylimidazole was the most depressive. These effects reversed at pH 4.3.
2. The ultraviolet absorption spectra of L-ascorbic acid-imidazole derivative-phosphate buffer system was measured, and the possibility of the complex formation between L-ascorbic acid and imidazole derivatives was examined.
3. The effects of these imidazole derivatives were also discussed as regards the differences in the contaminating Cu_??_ concentration.
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© The Japanese Biochemical Society
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