Journal of the Spectroscopical Society of Japan
Online ISSN : 1884-6785
Print ISSN : 0038-7002
ISSN-L : 0038-7002
Flash Photolysis of Aromatic Thiols in Aqueous Solution
Takeshi TAKAKURAKoichi FUJIOKAMasaki OKUYAMAHitoshi KAMADA
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1975 Volume 24 Issue 5 Pages 287-290

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Abstract
The flash photolysis of thiophenol and its derivatives in aqueous solutions produced the transients which had the strong absorptions with maxima at 470-600nm.The transients were assigned to the disulfide anion radicals. The decay of the radicals was first-order and the decay constants of some radicals were determined. It was suggested that the transition corresponding to the observed spectra should involve π-electron of rings.
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