BUNSEKI KAGAKU
Print ISSN : 0525-1931
Type analysis of n-paraffines and iso-paraffines by mass spectrometry
Shozo OSHIMA
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JOURNAL FREE ACCESS

1962 Volume 11 Issue 8 Pages 854-860

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Abstract
In the earlier papers reporting the mass-spectrometric type-analysis of paraffines, the objects were confined in C6C11 normal-paraffines or iso-paraffines with only one branch.
The author presents in this paper the mass-spectra of C6C22 paraffines obtained by a mass-spectrometer of high resolving power with a high temperature sample introduction device.
The results indicate that the type analysis with the combining use of the total sum of peakheights of CnH2n ion of M/e>42 (relative values with M/e 57 of n-hexane as the base peak.) and the molecular ion is successfully applicable to C12C22 paraffines.
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© The Japan Society for Analytical Chemistry
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