Cement Science and Concrete Technology
Online ISSN : 2187-3313
Print ISSN : 0916-3182
ISSN-L : 0916-3182
Cement Chemistry
ANALYSIS OF C3A HYDRATION WITH APPLICATION OF SURFACE COMPLEXATION MODEL
Kohei UEDA, Yuka MORINAGA, Toyoharu NAWA, Aoi HATAKEYAMA
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2015 Volume 69 Issue 1 Pages 29-36

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Abstract
The model of C3A-Gypsum hydration model is modified for considering existence of solid-solution of monosulfate and C-A-H in AFm phase, formation of C-A-H on the C3A particle surface, and diffuse double layer of C-A-H. In the hydration reaction, the phase equilibrium and the surface complexation reactions were assumed to be used in the model. For W/S=2.0, the hydration reaction proceeded by the phase of equilibrium. During early age of hydration for W/S=0.6, phase equilibrium and surface complexation caused the hydration process. At later age of hydration, not only the reaction between Ettringite and unhydrate but also Ettringite and C-A-H continuously occurred producing the AFm phase.
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