Cement Science and Concrete Technology
Online ISSN : 2187-3313
Print ISSN : 0916-3182
ISSN-L : 0916-3182
Cement Chemistry
INFLUENCE OF CALCIUM NITRITE ON THE HYDRATION OF HIGH VOLUME SLAG CEMENT
Etsuo SAKAIYukiko UEDAYutaka AIKAWANobukazu NITO
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2017 Volume 71 Issue 1 Pages 62-67

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Abstract

This paper discusses the influence of calcium nitrite and limestone powder on the strength and the hydration reaction of high volume slag cement (HVSC). By adding of calcium nitrite, the compressive strength of HVSC mortars are increased. The reaction of BFS similar to OPC is accelerated by calcium nitrite in HVSC. The acceleration of slag reaction by calcium nitrite is related to the formation of AFm(NO2). Therefore, though the reaction amount of BFS is increased, AFt is mainly formed by adding of calcium nitrite. The formation of AFt is important for the reduction of shrinkage of HVSC. By adding of both calcium nitrite and LSP, the strength of mortar is similar to that of mortar with calcium nitrite, but the total pore of hardened samples is decreased. This is a very important factor for the improvement of durability of HVSC.

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