Cement Science and Concrete Technology
Online ISSN : 2187-3313
Print ISSN : 0916-3182
ISSN-L : 0916-3182
Properties of Hardened Cement and Mortar
EFFECTS OF Ca/Si AND K/Na RATIOS AND DRYING TEMPERATURE ON THE FORMATION OF ASR PRODUCTS
Kennosuke SATOShigehiko SAITO
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2022 Volume 76 Issue 1 Pages 145-152

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Abstract

The present study experimentally examined the factors affecting the formation behavior of the alkali-silica reaction (ASR) products. In order to synthesize ASR products using reagents, samples were prepared by varying Ca/Si ratio, K/Na ratio and drying temperature, and the products and atomic bonding states of the synthesized samples were measured. As a result, ASR gels were stably formed with Ca/Si ratio in the range of 0.2 to 0.4. ASR gels were easily formed with high K/Na ratios, while C-S-H formation was predominant with low K/Na ratios. This may be due to the fact that Na-substituted C-S-H is more likely to form in the presence of large amounts of Na with low K/Na ratios. Only ASR gel was observed in the samples dried at 110℃, while crystalline material was also formed in the 50℃ dried samples. These results suggest that the products may change depending on the drying temperature.

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© Japan Cement Association
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