Cryobiology and Cryotechnology
Online ISSN : 2424-1555
Print ISSN : 1340-7902
Prediction of Glass Transition Temperature for Hydrophilic Polymer
Kiyoshi KAWAIKen FUKAMIPariya THANATUKSORNChotika VIRIYARATTANASAKKazuhito KAJIWARA
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JOURNAL FREE ACCESS

2011 Volume 57 Issue 2 Pages 117-120

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Abstract
Inulin was employed as a typical hydrophilic polymer, and glass transition temperature (T_g) of various types of inulin was investigated by using differential scanning calorimetry. The T_g of inulin samples decreased with increasing water content and decreasing molecular weight. The effect of water content on the T_g of inulin samples could be described by the Gordon-Taylor equation. Furthermore the effect of molecular weight on the T_g of anhydrous inulin samples could be described by a stretched exponential equation. From these results, the T_g of amorphous inulin can be predicted.
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© 2011 Japanese Society of Cryobiology and Cryotechnology
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