e-Journal of Soft Materials
Online ISSN : 1349-7308
ISSN-L : 1349-7308
Regular Article
Differential Dynamic Modulus of Carbon Black Filled, Uncured SBR in Single-Step Large Shearing Deformations
Youji SatohShuji FujiiSeiichi KawaharaYoshinobu IsonoShigeru Kagami
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Supplementary material

2007 Volume 3 Pages 29-40

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Abstract
Correspondence between nonlinear viscoelastic properties and change in various networks in carbon black (CB) filled, uncured SBRs has been studied by using combined measurements of relaxation modulus, differential dynamic modulus, and volume resisitivity in wide range of filler concentrations at various shear strains. Volume resistivity at no deformation showed step-off like change which can be explained by the percolation theory. This indicates formation of contact filler network at high filler loading. In addition, change in volume resistivity showed clear correspondence with linear-nonlinear transition in viscoelasticity. By the use of simple three-network model, contributions of contact filler, bridged filler, and entanglement networks to relaxation modulus were estimated. It was found that contact filler and bridged filler networks were dominant at lower and at higher filler concentrations, respectively. It was proposed, furthermore, that differential dynamic modulus can be used as the probes for changes in contact filler and bridged filler networks, respectively.
Estimation of effects of three kinds of networks, contact filler, polymer bridged filler, and chain entanglement networks, on strain dependent relaxation modulus at t=5 s for carbon black N330 filled, uncured SBRs. The bridged filler network is dominant at low CB concentration, and the contact filler network is at high concentration. Fullsize Image
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© 2007 The Society of Rubber Science and Technology, Japan
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