Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2002 Japanese Liquid Crystal Conference
Session ID : 3B01
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3B01 Interfacial tension in Dolymer-liquid crystal mixtures
*Akihiko Matsuyama
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Abstract
We theoretically study interfacial properties between two coexisting phases in mixtures of a flexible polymer and a low molecular weight liquid crystal. By numerically solving Euler equations for compositional and orientational order parameter fields, we calculate the order parameter profiles and interfacial tensions for nematic-isotopic and isotropic-isotropic phase equilibria. We find that the order parameter profiles are non-monotonic at some temperatures. The nematic-isotopic interfacial tension increases with decreasing temperature and is approximately proportional to (T - T_<NI>)^n at temperatures below the nematic-isotropic transition temperature (T_<NI>) of the pure nematogen. The value of the exponent n is strongly affected by the existence of a triple point.
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© 2002 Japanese Liquid Crystal Society
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