Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2014 Japanese Liquid Crystal Conference
Session ID : 3A07
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Rubbing effect on molecular alignment behavior by dynamic photopolymerization
*Masaki IshizuKyohei HisanoAtsushi Shishido
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Abstract

To improve various properties of specialty films, precise control of molecular alignment is important. The existing practical process to align anisotropic molecules is rubbing, while there are some problems; a static generation, contamination of dust. For overcoming these problems, we have found a new principle to induce molecular alignment. When photopolymerization of a mixture of anisotropic monomer, cross-linker and photoinitiator is carried out through a moving photomask, unidirectionally aligned polymer films can be obtained due to monomer diffusion. However, the detailed mechanism remains unexplored. In this study, effects of surface treatment and properties of liquid -crystalline monomers on molecular alignment are discussed. Furthermore, the molecular alignment mechanism is considered.

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© 2014 The Japanese Liquid Crystal Society
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