Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2016 Japanese Liquid Crystal Conference
Session ID : PB19
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Cholesteric Liquid Crystals of Diol Derivatives Leading to Glassy Solid-State Films
*Daiki KinoshitaTakurou IshizakiSeiichi Furumi
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Abstract

In this presentation, we report on synthesis and cholesteric liquid crystal (CLC) features of alkane diol derivatives tethering two cholesteryl units at their terminal positions (Cn-DiCh). An ethylene glycol derivative (C2-DiCh) cell showed a Bragg reflection band in a wavelength range from 620 nm to 780 nm by stepwise cooling from 142 °C to 125 °C. We serendipitously found that some of Cn-DiCh cells annealed at CLC temperatures are supercooled to 0 °C, whereupon the reflection wavelength can be preserved even at room temperature. Such supercooling treatment resulted in durable formation of a glassy CLC solid-state without the aid of any covalent bonding.

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© 2016 The Japanese Liquid Crystal Society
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