Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2020 Japanese Liquid Crystals Conference Online
Session ID : 1I04
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Design of ESIPT-based Fluorescent Molecules and Their Photophysical Properties in Liquid Crsytal Media
*Tsuneaki Sakurai
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Abstract

Rod-shaped molecules based on 2-(2-hydroxyphenyl)benzothiazole (HBT) were synthesized and their liquid crystalline (LC) behavior as well as luminescent property were investigated. The synthesized molecules show a large Stokes shift, avoiding the self-absorption and resulting in the transparency in the visible range. These compounds are extremely miscible to a conventional room-temperature nematic LC up to 14 wt%, and the resultant mixtures exhibit a sufficiently large photoluminescent quantum yield up to 0.32. The key for the large quantum yield in LC is the introduction of conjugated groups into HBT that suppresses the nonradiative decay pathways in the dispersed state.

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© 2020 The Japanese Liquid Crystal Society
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