Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2022 Japanese Liquid Crystals Conference
Session ID : 2BI3
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Supramolecular Polymer Topologies Exhibited by Hydrogen-Bonded Rosettes
Shiki Yagai
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Abstract

Hydrogen-bonded cyclic hexamers, so-called rosettes of π-conjugated molecules with barbituric acid unit undergo supramolecular polymerization in non-polar solvents through π-stacking interactions to form spontaneously (intrinsically) curved nanofibers. This intrinsic curvature enables the creation of supramolecular polymers with a variety of topologies (shapes), such as rings (toroids), helices, waves, spirals, and chains (polycatenanes). In addition, these supramolecular polymer assemblies have topology-dependent energy landscapes and also exhibit dynamic, diverse properties derived from hydrogen bonding.

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