Abstract
We have observed the two-step decrease in the dielectric constant ε of biass field and the current peaks representing the existence of SmCα* phase in several AFLCs. In high optical purity MHPOBC, with increasing temperature in SmCα* phase the, first decrease of ε was disappeared and the electric field at which the second-decrease of ε occurs was drastically increased. We discuss the dielectric behavior of the SmCβ* phase.