GEOCHEMICAL JOURNAL
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Micron-scale δ13C determination by NanoSIMS in a Juina diamond with a carbonate inclusion
Daniele L. PintiAkizumi IshidaNaoto TakahataYuji SanoHélène BureauPierre Cartigny
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Volume 50 (2016) Issue 4 Pages e7-e12

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Abstract

Juina diamonds present a wide spectrum of mineral inclusions, covering both peridotitic and eclogitic composition. Among the most rare inclusions, carbonates are interpreted as an evidence of deep recycling of sedimentary carbon into the transition zone or the lower mantle. Yet, the δ13C values measured in three FIB-TEM foils by NanoSIMS 50 of an alluvial diamond with a carbonate inclusion range between –8.85 ± 1.32‰ and –2.31 ± 1.88‰ with a mean total value of –5.0 ± 2.3‰. These values are in the range of typical mantle carbon, as measured in diamonds of peridotitic paragenesis. Similar δ13C values from –8.5 to –4.4‰ are reported in literature for five other Juina diamonds with carbonate inclusions. We can postulate either that the diamond is peridotitic and carbonate precipitated from fluids and survived to the reduction to diamond or that formed from reduction of carbonatitic melts in the upper mantle, percolating through eclogite.

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© 2016 by The Geochemical Society of Japan
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