NIPPON GOMU KYOKAISHI
Print ISSN : 0029-022X
STUDY ON BLEND-POLYMERS OF SULFUR-VULCANIZABLE ACRYYLIC ELASTOMER AND1, 2-POLYBUTADIENE (I) Effect of mixing temperatures on physical properties of blend-polymers
Yuji MINOURAShinzo YAMASHITAHidemasa YAMAGUCHIShinzo KOJIYATadao MATSUOMasanori KAKEIEtsuji UENOYAMA
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1978 Volume 51 Issue 11 Pages 878-883

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Abstract
1, 2polybutadine (1, 2-PB) was blended with sulfur-vulcanizable acrylic elastomer (ADM) in a mill at various temperatures and the effect of mixing temperature on physical properties of blend-polymers was studied.Green strength and hardness of unvulcanized compounds increased with an increase in mill temperature. It was revealed by electron micrographs that increasing mill temperature resulted in a change of continuous phase and of particle size.It is necessary to control mill temperature for the blend of ADM and 1, 2PB in a mill.State of phase continuities didn't change by press cure and vulcanizates of the same blend ratios having different phase continuities showed the same stress-strain curves, hardness and swelling, which suggested the presence of interphase crosslinking between different rubbers.
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© The Society of Rubber Industry, Japan
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