赤外・ラマン分光法による金属接着へのアプローチ - VBATDTとM10Pの混合溶液から生成する多様な化学吸着層の分子構造 -

山本 雅人; 鈴木 正子; 藤島 昭宏; 宮崎 隆; 久光 久; 小島 克則; 門磨 義則

doi:10.14832/gsjsdmd.2005f.0.13.0

46th General Session of the Japanese Society for Dental Materials and Devices

Session ID : A-13

DOI https://doi.org/10.14832/gsjsdmd.2005f.0.13.0

Conference information

Host: The Japanese Society for Dental Materials and Devices

General Presentations

Infrared and Raman Spectroscopic Studies on Adhesion between Metals and Functional Monomers - Molecular Structures of Chemisorbed Layers on Metals -

*Masato Yamamoto, Masako Suzuki, Akihiro Fujishima, Takashi Miyazaki, Hisashi Hisamitsu, Katsunori Kojima, Yoshinori Kadoma

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CONFERENCE PROCEEDINGS FREE ACCESS

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Abstract

Molecular structures of the organic films generated from the mixed solution of a 1,3,5-triazine-2,4-dithione (dithiol) derivative (VBATDT) and a phosphoric acid derivative (M10P) onto the various metal substrates were investigated by infrared and Raman spectroscopy. When the VBATDT is adsorbed on the metal, the heterocyclic group changes its structure from the thione form to the thiol form. Under the condition that the competitive adsorption is occurred, four different chemisorbed layers were formed.

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