RESEACH REPORTS National Institute of Technology,Hachinohe College
Online ISSN : 2433-2003
Print ISSN : 0385-4124
ISSN-L : 0385-4124
Synergistic Extraction of Rare Earth Elements with 2-Thenoyltrifluoroacetone and Di (2-pyridyl) pyrazole
Shigeto NAKAMURAHaruka SHIMADA
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RESEARCH REPORT / TECHNICAL REPORT FREE ACCESS

2008 Volume 43 Pages 75-80

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Abstract
The synergistic extraction of rare earth elements (III) has been investigated by a mixture of 2-thenoyltrifluoroacetone (HA) and 3,5-di (2-pyridyl) pyrazole (dpp) as a neutral ligand (S). Large synergistic enhancement was produced owing to the formation of the adduct complexes such as MA_ЗS. Extraction constants of rare earth elements with Htta in the absence and the presence of the neutral ligand were evaluated. The adduct formation constants have a similar value for La to Er and slightly decrease for heavier lanthanoids.
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© 2008 National Institute of Technology,Hachinohe College
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