Article ID: ISIJINT-2020-018
The research aimed to detect the rate of hydrogen absorption into Fe with rust layer during atmospheric corrosion in humidity-controlled air, and to realize the effect of relative humidity (RH) on hydrogen absorption rate. One side of an Fe plate specimen was covered by electrochemical Ni plate and the other side was covered with rust layer containing NaCl. The specimen was set between the double cells for electrochemical hydrogen permeation test. The cell for hydrogen detection was filled with 1 kmol·m-3 NaOH solution and the Ni side of the specimen was subjected to 0 VAg/AgCl in the solution. The cell for hydrogen absorption was filled with the air with a controlled RH to make the rust layer side corrode. During the corrosion, a hydrogen absorption current and an RH were continuously monitored. In the tests, the following results were obtained. In the region of RH between 42 and 74%, a hydrogen absorption rate increased with an increase in an RH. At an RH of 80%, a hydrogen absorption rate suddenly decreased. In the region of RH between 80 to 95%, a hydrogen absorption rate again increased with an increase in an RH. The pH in the rust layers during the corrosion under the tested RH range was estimated to be 4.2 and 4.3, slightly acidic.
