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We have proposed a new brighter LCD backlight using highly scattering optical-transmission (HSOT) polymer. This polymer material consists of specified microscopic heterogeneous structures inside the polymer. The high-order scattering phenomenon in the HSOT polymer was exactly investigated by Monte Carlo simulation based on Mie scattering theory. We obtained a good agreement between the calculated and the experimental results. The scattering property inside the HSOT polymer can be optimized for the LCD backlight by using this simulation program. As the result, our back-light system consisting of the HSOT polymer plate has simpler system, brighter luminance, and better luminance profile. The property of our backlight system which was actually applied to the LCD is shown.