Tourmalines from the Kiura emery deposit have been identified as Ca type and Na type Oxy-tourmaline. They are new tourmalines. Ca oxy tourmaline with high Al content is CaFe2AlAl6(AlSi5)O18(BO3)3(OH)3O . Na oxy tourmaline is NaAl3Al4Fe2Si6O18(BO3)3(OH)3O.