JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Thermodynamics, Physical Properties and Molecular Simulation
Hysteresis in Dissociation and Reformation of Methane Hydrate Crystal
Kazunari Ohgaki, Takeshi Sugahara, Shinya Nakano
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1999 Volume 32 Issue 2 Pages 235-236

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Abstract
A methane hydrate crystal annealed at maximum pressure remembers the compression in the hydrate S-cage until the higher equilibrium temperature for maximum pressure is reached. The hydrate S-cage-like structure in the aqueous solution also remembers the compression until the so-called activation energy is given by heating. Therefore, the hydrate crystal compressed by the maximum pressure is reformed at the equilibrium temperature for the maximum pressure.
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© 1999 The Society of Chemical Engineers, Japan
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