JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Thermodynamics, Physical Properties and Molecular Simulation
Application of Power-Law Formalism Method to Equilibrium Computation of Vapor Growth Epitaxy
Takahiro Hasegawa, Hideo Takatani, Jin Yoshimura
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1999 Volume 32 Issue 4 Pages 506-513

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Abstract
Modeling and numerical solutions of vapor phase epitaxy are limited because of convergence ability and a large number of iterations. To overcome these limitations, for the first time two Newton-like methods have been applied to models of vapor phase epitaxy for GaAs and InxGa1–xP: The Newton-Raphson method (NRM) and the power-law formalism method (PLFM). We compare the performances of the two methods in terms of the ability of convergence and the iteration numbers. The results indicate that PLFM is always significantly superior to NRM. All calculations by PLFM successfully converge from a rough estimated initial values for equilibrium partial pressures, where NRM can not. These results suggest that the limitation in the numerical calculations of the vapor growth epitaxy can be widely extended by the application of PLFM.
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© 1999 The Society of Chemical Engineers, Japan
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