JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Separations
Purity of m-Chloronitrobenzene Agglomerates from Batch Seeded Suspension Crystallization
Kunio FunakoshiHiroshi TakiyamaMasakuni Matsuoka
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1999 Volume 32 Issue 4 Pages 527-529

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Abstract
Morphology and purity of crystalline particles of m-chloronitrobenzene (m-CNB) from a batch suspension crystallizer were experimentally examined for the m-CNB and o-CNB eutectic system. There are two types in product particles, agglomerates and non-agglomerates. The agglomerates are constituted by several elementary crystals whose sizes are almost equal to the number-based mean size of non-agglomerates. The purity of agglomerates is lower than non-agglomerates and decreases with increasing size. This is caused by entrainment of mother liquor in the bridges during agglomeration.
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© 1999 The Society of Chemical Engineers, Japan
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