JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Separation Engineering
Kinetics of Gallium Extraction with 2-Ethylhexylphosphonic Acid Mono-2-Ethylhexyl Ester in the Presence of 5-Chloro-8-Quinolinol
Kazuo KondoMichiaki Matsumoto
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2006 Volume 39 Issue 3 Pages 292-297

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Abstract
In order to clarify the kinetics of the synergistic extraction of gallium with the mixed extractant of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHPNA) and 5-chloro-8-quinolinol, the initial extraction rate of gallium with the mixed extractant was measured using a stirred transfer cell.
Based on the knowledge of the extraction mechanism of gallium with EHPNA or 5-chloro-8-quinolinol alone and the synergistic extraction equilibrium of gallium with the mixed extractant, the synergistic extraction mechanism of gallium with the mixed extractant of EHPNA and 5-chloro-8-quinolinol was clarified. The experimental data were well explained by the model presented in this article without any adjustable parameters.
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© 2006 The Society of Chemical Engineers, Japan
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