Materials Engineering and Interfacial Phenomena
Synthesis of ZnO Particles by Parallel Flow Precipitation Hydrothermal Process and their Photocatalytic Performance
2016 Volume 49 Issue 2 Pages 191-196
Details
2016 Volume 49 Issue 2 Pages 191-196
ZnO particles were synthesized by a parallel flow precipitation hydrothermal process with Zn(NO3)2·6H2O and NH3·H2O as raw materials. The morphology and structure of as-synthesized ZnO particles were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and Brunauer-Emmett-Teller (BET) surface area analysis. The results revealed that all of the obtained ZnO samples had a hexagonal wurtzite structure, with the precipitation reaction pH being a key factor in the formation of the hexagonal prism structure. The photocatalytic activity of ZnO was evaluated via Rhodamine B (RhB) dye degradation. The ZnO-3 sample synthesized at a precipitation pH=6.8 possessed excellent photocatalytic degradation efficiency after three photocatalytic experiments. No significant change of photocatalytic activity could be detected when NO3− was added, however, the presence of SO42− and Cl− reduced the photocatalytic activity, with SO42− most severely reducing activity.
