JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Chemical Reaction Engineering
Utilization of Modified Red Mud as a Heterogeneous Base Catalyst for Transesterification of Canola Oil
Agus Wahyudi Winarto KurniawanHirofumi Hinode
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2017 Volume 50 Issue 7 Pages 561-567

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Abstract

The present study investigates the use of modified red mud as a solid base catalyst for biodiesel production. Red mud, a waste from the Bayer process, was treated using soda-lime calcination at various temperatures. The modified red mud was characterized using TG-DTA, XRD, SEM, BET and the Hammett indicator method. The catalytic activity was investigated for the transesterification of canola oil with methanol to biodiesel with a yield of more than 99% under the following conditions: 12 : 1 methanol/oil molar ratio, 4 wt% catalyst concentration, 60°C reaction temperature, and 2 h reaction time. Furthermore, the catalyst can be reused for up to three cycles without any significant loss of activity.

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© 2017 The Society of Chemical Engineers, Japan
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